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Updated: May 21, 2026
10:42
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Bis[hexa-amminecobalt(III)] penta-chloride nitrate
1Department of Materials and Chemical Engineering, Ministry of Education Key Laboratory of Advanced Materials of Tropical Island Resources, Hainan University, Haikou 570228, People's Republic of China.
Summary
A novel cobalt(III) coordination compound, [Co(NH3)6]2Cl5(NO3), was synthesized using hydrothermal methods. This study details its crystal structure, revealing a 3D network formed by hydrogen bonds between cobalt complexes and anions.
Area of Science:
- Inorganic Chemistry
- Crystallography
- Materials Science
Background:
- Hydrothermal synthesis offers a route to novel coordination compounds.
- Understanding crystal structures is crucial for predicting material properties.
Purpose of the Study:
- To synthesize and characterize a new cobalt(III) coordination compound.
- To elucidate the crystal structure and bonding of [Co(NH3)6]2Cl5(NO3).
Main Methods:
- Hydrothermal synthesis was employed for compound preparation.
- Single-crystal X-ray diffraction was used to determine the crystal structure.
- Analysis of bond distances, coordination geometry, and hydrogen bonding interactions.
Main Results:
- The title compound, [Co(NH3)6]2Cl5(NO3), was successfully synthesized.
- The crystal structure features three Co(3+) ions and [Co(NH3)6]3+ octahedra.
- A three-dimensional network is formed via N-H⋯O and N-H⋯Cl hydrogen bonds.
Conclusions:
- The study successfully characterized a new cobalt(III) complex.
- The intricate hydrogen bonding network dictates the compound's solid-state structure.
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