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Electron irradiation effects on optical properties of semiorganic antimony thiourea tetra chloride single crystals

K Mahesha Upadhya1, N K Udayashankar, S Ganesh

  • 1Department of Physics, National Institute of Technology Karnataka, Surathkal, P.O. Srinivasnagar 575025, Karnataka, India. mahesh.upadhya@yahoo.com

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|June 30, 2012
PubMed

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In aromatic compounds, such as benzene, the circulation of (4n + 2) π-electrons sets up a diamagnetic or diatropic ring current around the perimeter of the molecule. This current induces a magnetic field that opposes the external field inside the ring and reinforces it on the outside. The protons in benzene are deshielded and exhibit high chemical shifts in the range 6.5–8.5 ppm. The shielding effect at the center of the ring is evident in complex aromatic molecules, such as annulenes. In...