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Can zinc really exist in its oxidation state +III?

Tobias Schlöder1, Martin Kaupp, Sebastian Riedel

  • 1Institut für Anorganische und Analytische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21, D-79104 Freiburg im Breisgau, Germany.

Journal of the American Chemical Society
|July 11, 2012
PubMed
Summary

Quantum chemical calculations reveal that the predicted Zn(III) complex, Zn(AuF6)3, is not thermochemically stable. Furthermore, its formation would not represent a true Zinc(III) oxidation state.

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