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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology
Volodymyr Bon1, Volodymyr Senkovskyy, Irena Senkovska
1Department of Inorganic Chemistry, Dresden University of Technology, Bergstr. 66, 01062 Dresden, Germany.
Chemical Communications (Cambridge, England)
|July 18, 2012
Abstract:
Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr(4+) or Hf(4+) source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.
