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Related Concept Videos

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
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In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this process,...
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The average temperature of Earth is the subject of much current discussion. Earth is in radiative contact with both the Sun and dark space; it receives almost all its energy from the radiation of the Sun and reflects some of it into outer space. Dark space is very cold, about 3 K, so Earth radiates energy into it. For instance, heat transfer occurs from soil and grasses, the rate of which can be so rapid that frost can occur on clear summer evenings, even in warm latitudes.
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UV–Vis Spectroscopy of Conjugated Systems

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TiO2-coated Hollow Glass Microspheres with Superhydrophobic and High IR-reflective Properties Synthesized by a Soft-chemistry Method
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Absorption to reflection transition in selective solar coatings.

Kyle D Olson1, Joseph J Talghader

  • 1Department of Electrical and Computer Engineering, University of Minnesota, 200 Union St. SE, Minneapolis, Minnesota 55455, USA.

Optics Express
|July 26, 2012
PubMed
Summary

Real-world selective solar absorbers require accounting for non-zero infrared emissivity. This study calculates the optimum transition wavelength for solar selective coatings with varying emissivity, revealing significant shifts from ideal models.

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Area of Science:

  • Materials Science
  • Optical Engineering
  • Renewable Energy

Background:

  • Ideal selective solar absorbers assume zero infrared emissivity, which is unachievable in real coatings.
  • Non-zero infrared emissivity significantly alters the optimal design parameters for solar absorbers.

Purpose of the Study:

  • To investigate the impact of non-zero infrared emissivity on the optimum transition wavelength for selective solar absorbers.
  • To calculate equilibrium temperatures and optimal wavelengths for various infrared emissivity values and solar spectra.

Main Methods:

  • Theoretical calculations for AM0 and AM1.5 solar spectra with infrared emissivity ranging from 0% to 5%.
  • Experimental and theoretical characterization of a four-layer sputtered Mo and SiO₂ coating.

Main Results:

  • An infrared emissivity of 5% shifts the optimum transition wavelength and affects equilibrium temperature.
  • A 5% emissivity with 10x AM1.5 solar concentration yields an optimum wavelength of 1.28 µm and 957K equilibrium temperature.
  • Demonstrated a sputtered Mo and SiO₂ coating with 5% infrared absorption.

Conclusions:

  • Realistic modeling of selective solar absorbers must incorporate non-zero infrared emissivity.
  • The study provides crucial data for designing efficient solar selective coatings with improved performance.