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Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
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Tailoring the exchange interaction in covalently linked basic carboxylate clusters through bridging ligand selection.

Pablo Alborés1, Christian Plenk, Eva Rentschler

  • 1Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE (CONICET), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina. albores@qi.fcen.uba.ar

Inorganic Chemistry
|July 27, 2012
PubMed
Summary

Researchers developed new iron-cobalt/nickel carboxylate clusters with unique {Fe(III)(2)M(II)O} motifs. These compounds exhibit tunable magnetic interactions, offering potential for advanced materials design.

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