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Updated: May 20, 2026
Ligand-Mediated Nucleation and Growth of Palladium Metal Nanoparticles
Published on: June 25, 2018
Palladium metal nanoparticle size control through ion paired structures of [PdCl4]2- with protonated PDMAEMA
Behzad Tangeysh1, Michael Fryd, Marc A Ilies
1Department of Chemistry, Temple University, Philadelphia, PA 19122, USA.
Abstract:
The mean diameter of palladium metal particles produced by citrate reduction of the (H(+))(n) PDMAEMA/[PdCl(4)](2-) aqueous system increases from 1.4 nm to 5.0 nm as the pH decreases from 6.3 to 3.3 and the (H(+))(n) PDMAEMA/[PdCl(4)](2-) species undergo conversion from a cross linked polymer network to a single chain structure.
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