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Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework: a double
Arshad Aijaz1, Abhi Karkamkar, Young Joon Choi
1National Institute of Advanced Industrial Science and Technology, Ikeda, Osaka 563-8577, Japan.
Abstract:
Ultrafine Pt nanoparticles were successfully immobilized inside the pores of a metal-organic framework, MIL-101, without aggregation of Pt nanoparticles on the external surfaces of framework by using a "double solvents" method. TEM and electron tomographic measurements clearly demonstrated the uniform three-dimensional distribution of the ultrafine Pt NPs throughout the interior cavities of MIL-101. The resulting Pt@MIL-101 composites represent the first highly active MOF-immobilized metal nanocatalysts for catalytic reactions in all three phases: liquid-phase ammonia borane hydrolysis, solid-phase ammonia borane thermal dehydrogenation, and gas-phase CO oxidation.
