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Updated: May 19, 2026

One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates
Published on: January 15, 2018
6-Hy-droxy-7,8-dimethyl-chroman-2-one
Shailesh K Goswami1, Lyall R Hanton, C John McAdam
1Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
Abstract:
The title compound, C(11)H(12)O(3), is essentially planar, with an r.m.s. deviation of 0.179 Å from the mean plane through the 14 non-H atoms in the mol-ecule. The benzene ring and the pyranone mean plane are inclined at 13.12 (6)° to one another and the pyran-one ring adopts a flattened chair conformation. In the crystal, O-H⋯O hydrogen bonds and C-H⋯O contacts form R(1) (2)(6) rings and link mol-ecules into chains along b. Additional C-H⋯O contacts generate inversion dimers, with R(2) (2)(8) ring motifs, and form sheets parallel to (-102) which are linked by C-H⋯π interactions.
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