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Redox-switchable resorcin[4]arene cavitands: molecular grippers

Igor Pochorovski1, Marc-Olivier Ebert, Jean-Paul Gisselbrecht

  • 1Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|August 22, 2012
PubMed
Summary

Novel diquinone-based cavitands switch between open and closed states via redox control, enabling guest binding and release. This molecular switch relies on redox-dependent intramolecular hydrogen bonding for stability.

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