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Total syntheses of (±)-securinine and (±)- allosecurinine

Jung-Hsuan Chen1, Samantha R Levine, Jonas F Buergler

  • 1Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.

Organic Letters
|August 24, 2012
PubMed

Abstract:

Total syntheses of (±)-securinine and (±)-allosecurinine that employ a tandem rhodium carbenoid-initiated Claisen/α-ketol rearrangement sequence as a key step are described.

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