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Coronenediimides synthesized via ICl-induced cyclization of diethynyl perylenediimides

Qifan Yan1, Kang Cai, Chenhao Zhang

  • 1Beijing National Laboratory of Molecular Sciences, Department of Applied Chemistry, College of Chemistry, Peking University, Beijing 100871, China.

Organic Letters
|August 28, 2012
PubMed

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Characteristics of the diene
Conformation
The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is more stable, the...
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