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Updated: Jul 24, 2026

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis
Published on: January 6, 2016
Covalent attachment of catalyst molecules to conductive diamond: CO2 reduction using "smart" electrodes
Shu A Yao1, Rose E Ruther, Linghong Zhang
1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States.
Abstract:
We report here covalent attachment of a catalytically active cobalt complex onto boron-doped, p-type conductive diamond. Peripheral acetylene groups were appended on a cobalt porphyrin complex, and azide-alkyne cycloaddition was used for covalent linking to a diamond surface decorated with alkyl azides. The functionalized surface was characterized by X-ray photoelectron spectroscopy and Fourier transform IR spectroscopy, and the catalytic activity was characterized using cyclic voltammetry and FTIR. The catalyst-modified diamond surfaces were used as "smart" electrodes exhibiting good stability and electrocatalytic activity for electrochemical reduction of CO(2) to CO in acetonitrile solution.
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