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Updated: May 18, 2026
10:42
Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
N-[(4-Chloro-phen-yl)sulfon-yl]acetamide
Acta Crystallographica. Section E, Structure Reports Online
|September 13, 2012
Summary
This study details the crystal structure of a compound containing two independent molecules. These molecules form infinite chains through hydrogen bonds and exhibit short intermolecular chlorine-chlorine contacts.
Area of Science:
- Crystallography
- Chemical structure analysis
- Molecular interactions
Background:
- The compound C(8)H(8)ClNO(3)S presents unique structural features.
- Understanding molecular arrangements is crucial in chemical research.
Purpose of the Study:
- To elucidate the crystal structure of C(8)H(8)ClNO(3)S.
- To analyze the intermolecular interactions within the crystal lattice.
Main Methods:
- X-ray crystallography was employed to determine the crystal structure.
- Analysis of dihedral angles and hydrogen bonding patterns.
Main Results:
- The asymmetric unit contains two crystallographically independent molecules (A and B).
- Dihedral angles between the benzene and amide planes are approximately 87.6° and 86.0°.
- Molecules form infinite chains via N-H⋯O hydrogen bonds along the b axis.
- Short intermolecular Cl⋯Cl contacts (3.2882(5) and 3.2812(5) Å) were observed.
Conclusions:
- The crystal structure reveals a specific arrangement of two independent molecules.
- Hydrogen bonding and Cl⋯Cl contacts play a significant role in the crystal packing.
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