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1,3,4-Oxadiazole containing silanes as novel hosts for blue phosphorescent organic light emitting diodes

Man-kit Leung1, Wan-Hsi Yang, Ching-Nan Chuang

  • 1Department of Chemisty, National Taiwan University, 1 Roosevelt Road Section 4, Taipei 106, Taiwan, R.O.C. mkleung@ntu.edu.tw

Organic Letters
|September 25, 2012
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Aryldiazonium Salts to Azo Dyes: Diazo Coupling

The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.