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Updated: May 18, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Crystal growth, structure, and magnetic properties of a two-dimensional triangular lattice magnet, Cu2(OH)3HCO2
Wataru Fujita1, Koichi Kikuchi, Wasuke Mori
1Department of Chemistry, Tokyo Metropolitan University, Minami-osawa 1-1, Hachioji 192-0397, Japan. fujitaw@tmu.ac.jp
Abstract:
We prepared single crystals of basic copper formate Cu(2)(OH)(3)HCO(2) (1) by hydrolysis of formate anions in an aqueous solution of copper formate. X-ray structure analysis showed that this material has a two-dimensional triangular lattice network with S = 1/2. The temperature dependence of magnetic susceptibility revealed antiferromagnetic ordering at 5.4 K. A spin-flop transition was observed at about 20 kOe at 2 K, thereby indicating metamagnetic-like behavior. The saturation magnetization was almost one-half of the theoretical value at 2 K under 70 kOe. The magnetic behaviors of 1 were also discussed with regard to its crystal structure. The preparation method presented herein is convenient and available for single crystal growth of metal hydroxide derivatives with various anions.
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