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First-passage time: lattice versus continuum.

Kamal Sharma1, N Kumar

  • 1Raman Research Institute, Bangalore 560080, India.

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|October 4, 2012
PubMed
Summary
This summary is machine-generated.

This study revises classical diffusion calculations for discrete lattices, modifying a key boundary condition for accurate first-passage probability density. The findings offer a new analytical method for barrier escape problems.

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Area of Science:

  • Statistical Physics
  • Computational Physics
  • Quantum Mechanics

Background:

  • Classical diffusion on a continuum uses Schrödinger's integral equation for first-passage probability density.
  • Diffusion by hopping on discrete lattices presents unique challenges for this calculation.
  • Existing boundary conditions, derived for continuous systems, require re-evaluation for discrete models.

Purpose of the Study:

  • To revisit the Schrödinger's integral equation approach for calculating first-passage probability density in discrete lattice diffusion.
  • To identify and modify the boundary condition necessary for accurate calculations in discrete systems.
  • To derive an analytical expression for first-passage density in a specific discrete model.

Main Methods:

  • Revisiting the integral equation approach for discrete lattice diffusion.
  • Modifying the boundary condition based on normalization requirements.
  • Deriving an analytical expression for a three-site barrier escape model.

Main Results:

  • A modified boundary condition is identified as crucial for discrete lattice diffusion.
  • The normalization condition uniquely determines the required boundary condition.
  • An explicit analytical expression for first-passage density is derived for a three-site model.

Conclusions:

  • The standard boundary condition for continuous diffusion needs modification in discrete lattice hopping.
  • The normalization condition is sufficient to determine the correct boundary condition for discrete systems.
  • The derived analytical expression provides a method for modeling escape over barriers in discrete systems.