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Interactive Molecular Model Assembly with 3D Printing
Published on: August 13, 2020
Building on architectural principles for three-dimensional metallosupramolecular construction
Maarten M J Smulders1, Imogen A Riddell, Colm Browne
1Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.
Chemical Society Reviews
|October 4, 2012
Summary
This review explores metallosupramolecular self-assembly, focusing on non-classical 3D architectures beyond Platonic solids. It details designs using single ligands, heteroleptic, and heterometallic structures for advanced functionality.
Area of Science:
- Supramolecular Chemistry
- Materials Science
- Coordination Chemistry
Background:
- Metallosupramolecular self-assembly has advanced significantly over 20 years.
- Design principles based on ligand and metal coordination geometry enable rational design of classical architectures.
Purpose of the Study:
- This review focuses on recent developments in designing and synthesizing 3D suprastructures with non-classical architectures.
- It addresses secondary effects driving the formation of these complex structures.
Main Methods:
- Discussion of three classes of metallosupramolecular assemblies: single ligand-metal, heteroleptic, and heterometallic structures.
- Analysis of design principles and secondary effects influencing the formation of non-classical architectures.
Main Results:
- Detailed examination of metallosupramolecular assemblies with non-classical, non-Archimedean/Platonic solid architectures.
- Identification of secondary effects crucial for the formation of these complex 3D structures.
Conclusions:
- The review highlights strategies for creating complex metallosupramolecular architectures.
- It suggests combining principles from different assembly classes to enhance complexity and functionality.
