Related Experiment Video
Updated: May 17, 2026

09:31
Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices
Published on: March 27, 2019
Which controls wetting? Contact line versus interfacial area: simple experiments on capillary rise
1Entegris, Inc., Chaska, Minnesota 55318, United States. chuck_extrand@entegris.com
Langmuir : the ACS Journal of Surfaces and Colloids
|October 24, 2012
Summary
Wetting phenomena in capillary rise are driven by interactions at the contact line, not just interfacial areas. Experiments show the contact line
Area of Science:
- Physics
- Surface Science
- Fluid Dynamics
Background:
- Wetting phenomena, crucial in various scientific and industrial applications, can be described using models based on capillary forces, Laplace pressure, or solid surface energies.
- Understanding the factors governing capillary rise, such as the interplay between contact lines and interfacial areas, is essential for predicting fluid behavior in confined geometries.
Purpose of the Study:
- To investigate the relative significance of the contact line and interfacial areas in capillary rise within small-diameter glass tubes.
- To experimentally determine the primary drivers of wetting phenomena in this specific context.
Main Methods:
- Conducted a series of simple experiments using small-diameter glass tubes.
- Focused on observing and analyzing the capillary rise phenomenon.
- Examined the role of interactions near the contact line and overall interfacial areas.
Main Results:
- Experimental observations indicate that capillary rise is predominantly influenced by interactions occurring at the contact line.
- The contribution of interfacial areas to the overall phenomenon was found to be less significant compared to contact line interactions.
Conclusions:
- The study concludes that wetting phenomena, specifically capillary rise in small glass tubes, are primarily governed by the physics of the contact line.
- These findings highlight the critical role of localized interactions at the fluid-solid interface in driving capillary action.
More Related Videos
Related Concept Videos
Rise of Liquid in a Capillary Tube
When very thin cylindrical tubes, called capillaries, are dipped in a liquid, the liquid rises or falls in the tube compared to the surrounding liquid. This phenomenon is called capillary action. Capillary action occurs due to the combination of two opposing forces: the cohesive forces of the liquid, which cause it to stick to itself and form a rounded shape, and the adhesive forces between the liquid and the walls of the container, which cause the liquid to be attracted to the container walls.
Capillarity in Fluid
Capillarity describes the movement of liquid in small spaces without external forces acting on it. The capillarity is driven by surface tension and adhesive interactions between the liquid and surrounding solid surfaces. This effect is often seen in narrow tubes, porous materials, and fine particles.
Surface tension is crucial to capillarity. It results from cohesive forces between liquid molecules at the liquid-air boundary, forming a skin that resists external forces. When the capillary tube...
Surface tension is crucial to capillarity. It results from cohesive forces between liquid molecules at the liquid-air boundary, forming a skin that resists external forces. When the capillary tube...
Surface Tension, Capillary Action, and Viscosity
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
Contact Angle
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive force...
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive force...
Surface Tension
Surface tension is defined as the force per unit length (γ) acting along the surface of a liquid. It arises due to strong intermolecular forces of attraction. A molecule located inside the bulk of the liquid is surrounded by other molecules and experiences equal forces in all directions. However, a molecule at the surface experiences unbalanced forces because there are more neighboring molecules below than above. This creates a net inward force that pulls surface molecules toward the interior,...
Surface Tension of Fluid
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies with...
Surface tension varies with...

