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Hysteretic carbon dioxide sorption in a novel copper(II)-indazole-carboxylate porous coordination polymer
Chris S Hawes1, Ravichandar Babarao, Matthew R Hill
1Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand.
Chemical Communications (Cambridge, England)
|October 25, 2012
Abstract:
The synthesis, structural and gas sorption studies of a porous Cu(II) coordination polymer featuring 1H-indazole-5-carboxylic acid (H(2)L) are presented. [Cu(HL)(2)] is a thermally and hydrolytically robust 4-connected 3D coordination polymer of NbO topology and is replete with 1D channels that permit selective and hysteretic sorption of CO(2).
