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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Poly[μ(3)-aqua-aqua(μ(3)-3,5-dinitro-benzoato-κO(1):O(3):O(5))caesium]
1Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.
Abstract:
In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitro-benzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water mol-ecules (one triply bridging and the other monodentate) and four O-atom donors from two nitro groups and one bridging carboxyl-ate O-atom donor from the ligand. Intra-unit O-H⋯O hydrogen-bonding inter-actions involving both water mol-ecules are observed in the three-dimensional polymeric complex structure.
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