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06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(4-Meth-oxy-phen-yl)(4-methyl-cyclo-hex-yl)methanone
1Graduate School, Tianjin Medical University, Tianjin 300070, People's Republic of China ; Tianjin Key Laboratory of Molecular Design & Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin 300193, People's Republic of China.
Acta Crystallographica. Section E, Structure Reports Online
|November 6, 2012
Summary
This study details the crystal structure of a C(15)H(20)O(2) compound, revealing two similar molecules in its asymmetric unit. These molecules form chains in the crystal through weak hydrogen bonding interactions.
Area of Science:
- Crystallography
- Organic Chemistry
- Solid-State Chemistry
Background:
- Understanding the solid-state structure of organic compounds is crucial for predicting their physical and chemical properties.
- The specific compound C(15)H(20)O(2) has not been previously characterized in detail regarding its crystalline form.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(15)H(20)O(2).
- To analyze the molecular geometry and intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the crystal structure.
- Analysis of bond lengths, bond angles, and intermolecular contacts was performed.
Main Results:
- The title compound, C(15)H(20)O(2), crystallizes with two independent molecules of similar geometry in the asymmetric unit.
- The cyclohexyl ring within each molecule adopts a chair conformation.
- Weak C-H⋯O interactions link translationally related molecules into chains along the a-axis.
Conclusions:
- The crystal packing of C(15)H(20)O(2) is governed by specific intermolecular interactions.
- The conformational preferences of the cyclohexyl ring influence the overall molecular arrangement in the solid state.
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