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Tribenzotriquinacene: a versatile synthesis and C3-chiral platforms

Georgios Markopoulos1, Lars Henneicke, Jun Shen

  • 1Institut für Organische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.

Angewandte Chemie (International Ed. in English)
|November 13, 2012
PubMed
Abstract

No abstract available in PubMed .

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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...