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Solid-phase Synthesis of [4.4] Spirocyclic Oximes
Published on: February 6, 2019
A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural
Andrey V Protchenko1, Andrew D Schwarz, Matthew P Blake
1Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, UK.
Abstract:
Si in sight: a one-pot, single-step synthesis of an acyclic silylsilylene, Si{Si(SiMe(3))(3)}{N(SiMe(3))Dipp} (Dipp=2,6-iPr(2)C(6)H(3)), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.
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