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The self-assembly of a macroion with anisotropic surface charge density distribution
Fadi Haso1, Xikui Fang, Panchao Yin
1Department of Chemistry, Lehigh University, Bethlehem, PA, USA.
Abstract:
A macroion, having anisotropic surface charge density distribution, shows unique self-assembly behaviour in polar solvents. Regular "blackberry"-like assemblies form in methanol-water mixtures due to counter-ion mediated attraction and the strong contribution of hydrogen bonding. However, rod-like assemblies form in acetone-water mixtures as the charge inhomogeneity effect overcomes the non-directional hydrogen bonding.
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