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In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
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Kink localization under asymmetric double-well potentials.

Emilio N M Cirillo1, Nicoletta Ianiro, Giulio Sciarra

  • 1Dipartimento di Scienze di Base e Applicate per l'Ingegneria, Sapienza Università di Roma, via A. Scarpa 16, I-00161 Roma, Italy. emilio.cirillo@uniroma1.it

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|December 11, 2012
PubMed
Summary
This summary is machine-generated.

The position of diffuse phase interfaces in asymmetric potentials is not symmetric and depends on the potential

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Area of Science:

  • Materials Science
  • Chemical Physics
  • Thermodynamics

Background:

  • Diffuse phase interfaces are crucial in various physical phenomena.
  • Asymmetric double-well potentials with degenerate minima present complex interface behaviors.

Purpose of the Study:

  • To analyze the characteristics of diffuse phase interfaces under asymmetric potentials.
  • To determine the factors governing the symmetry and position of these interfaces.

Main Methods:

  • Mathematical modeling of diffuse interfaces.
  • Analysis of potential energy landscapes with degenerate minima.
  • Asymptotic analysis for small interface energy costs.

Main Results:

  • The limiting sharp interface profile is generally asymmetric.
  • Interface position is determined solely by the second derivatives of the potential at the minima.
  • Demonstrated application to solid-fluid segregation in porous media.

Conclusions:

  • Interface asymmetry is a key feature under specific potential conditions.
  • Potential energy landscape dictates interface location, not just interface energy.
  • The findings offer insights into phase segregation in materials and porous media.