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Enantioselective synthesis of intrinsically chiral mercury sulfide nanocrystals

Assaf Ben-Moshe1, Alexander O Govorov, Gil Markovich

  • 1School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv, 69978, Israel.

Angewandte Chemie (International Ed. in English)
|December 13, 2012
PubMed
Abstract

No abstract available in PubMed .

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...