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Updated: May 15, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
A dinuclear alkynylplatinum(II) pyridinedicarboxamide: conformational change-induced switching of emission properties
Annika Gross1, Toshiyuki Moriuchi, Toshikazu Hirao
1Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan.
Abstract:
The synthesis and characterisation of a dinuclear pyridinedicarboxamide-platinum(II) complex exhibiting tunable optical properties based on metal-metal interaction are reported. Conformational change-induced switching between metal-to-ligand charge-transfer and metal-metal-to-ligand charge-transfer emission properties by the influence of methanol was demonstrated.
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