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Updated: May 15, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
4-(2-Chloro-phenyl-amino)-pent-3-en-2-one
Gertruida J S Venter1, Alice Brink, Gideon Steyl
1Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein, 9300, South Africa.
Abstract:
In the title compound, C(11)H(12)ClNO, intra-molecular N-H⋯O hydrogen bonding is present. The dihedral angle between the benzene ring and the pentenone unit is 46.52 (5)°. In the crystal, C-H⋯O inter-actions between hydrogen atoms of the aryl moiety and two separate oxygen atoms occur, leading to a three-dimensional network.
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