Sulfur as a selective 'soft' oxidant for catalytic methane conversion probed by experiment and theory

Qingjun Zhu1, Staci L Wegener, Chao Xie

  • 1Department of Chemistry and the Center for Catalysis and Surface Science, Northwestern University, Evanston, Illinois 60208-3113, USA.

Nature Chemistry
|January 25, 2013
PubMed
Summary

Elemental sulfur enables selective methane conversion to ethylene using novel catalysts. Stronger metal-sulfur bonds on catalyst surfaces enhance ethylene selectivity by minimizing methane over-oxidation.

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