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A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties
Yong-Liang Huang1, Yun-Nan Gong, Long Jiang
1MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Chemical Communications (Cambridge, England)
|January 25, 2013
Abstract:
A porous Mg-based 3D metal-organic framework with unique nanoscale cages and two-fold interpenetrating pcu nets has been synthesized and characterized. It shows gas-uptake capacities for N(2), H(2), O(2) and CO(2) at low temperatures and selective adsorption of CO(2) over O(2) and N(2) at room temperature.
