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Updated: May 14, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Doubly interpenetrated chiral (10,3)-a network with charge-transfer-type guest inclusion
Lei Han1, Lan Qin, Lan-Ping Xu
1State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science & Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China. hanlei@nbu.edu.cn
Abstract:
A doubly interpenetrated metal-organic framework, [Zn(3)(TATB)(2)(H(2)O)(2)](n) (2), with chiral (10,3)-a topology, has been synthesized from an achiral, trigonal-planar ligand, 4,4',4″-s-triazine-2,4,6-triyltribenzoate (TATB). The large chiral channels in 2 act as scaffolds for the inclusion of N,N-dimethylaniline (DMA) molecules by donor-acceptor interactions. The resulting host-guest composite, DMA@2, shows desirably intense luminescence, which originated from photoinduced charge-transfer interactions in excited states.
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