Related Experiment Video
Updated: May 14, 2026

10:13
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
Published on: April 28, 2023
An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and
Huabin Zhang1, Ping Lin, Xiaochen Shan
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
Abstract:
The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd(7)Rb}(n) helix and nanoscale {Cd(16)Rb(4)} and {Cd(18)Rb(2)} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.
