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Related Concept Videos

Adsorption of Gases on Solids01:28

Adsorption of Gases on Solids

Adsorption is a process where molecules, known as the adsorbates, accumulate on a surface, which is referred to as the adsorbent or substrate. Occurring at the solid-gas interface, this phenomenon is crucial in various scientific and industrial contexts. The reverse of adsorption is desorption.Two types of adsorptions exist: physical (physisorption) and chemical (chemisorption). Physisorption involves gas molecules held to the solid's surface by relatively weak intermolecular van der Waals...
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Brunauer, Emmett, and Teller (BET) introduced a theory in 1938 that modified Langmuir's assumptions to explain multilayer physical adsorption. This theory is applicable to Type II isotherms and provides a more realistic picture of adsorption processes. The BET theory assumes a uniform solid surface with localized adsorption sites, where adsorption at one site doesn't affect adsorption at neighboring sites. This theory also allows for the possibility of additional molecules being adsorbed on top...
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Adsorption isotherms are mathematical models that describe how molecules in a gas or liquid phase interact with surfaces. Two of the most common isotherm models are the Langmuir and Freundlich isotherms, which relate to Type I monolayer chemisorption. The Langmuir model is based on four key assumptions:• Adsorption cannot exceed monolayer coverage.• All surface sites are equivalent.• Molecules adsorb only at vacant sites.• There are no interactions between adsorbed molecules.Consider the...
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Related Experiment Video

Updated: May 14, 2026

A Synthetic Methodology for Preparing Impregnated and Grafted Amine-Based Silica Composites for Carbon Capture
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Published on: September 29, 2023

Activated carbon spheres for CO2 adsorption.

Nilantha P Wickramaratne1, Mietek Jaroniec

  • 1Department of Chemistry and Biochemistry, Kent State University, Kent, Ohio 44242, USA.

ACS Applied Materials & Interfaces
|February 13, 2013
PubMed
Summary

Researchers developed activated carbon spheres (ACS) with high surface area and micropore volume. These advanced carbon materials exhibit excellent carbon dioxide (CO2) adsorption capacities, making them promising for gas capture applications.

Area of Science:

  • Materials Science
  • Chemical Engineering
  • Environmental Science

Background:

  • Phenolic resin spheres are synthesized using a modified Stöber method.
  • Carbonization of these spheres yields carbon spheres (CS).
  • Activation of CS is crucial for enhancing their adsorption properties.

Purpose of the Study:

  • To synthesize activated carbon spheres (ACS) with high surface area and micropore volume.
  • To investigate the CO2 adsorption performance of the synthesized ACS.
  • To evaluate the potential of ACS for carbon capture applications.

Main Methods:

  • One-pot modified Stöber method for synthesizing phenolic resin spheres.
  • Carbonization of phenolic resin spheres to produce carbon spheres (CS).

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09:46

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Published on: August 25, 2016

  • CO2 activation of CS to obtain activated carbon spheres (ACS).
  • Measurement of CO2 adsorption capacities at different temperatures and pressures.
  • Main Results:

    • Synthesized ACS possess diameters ranging from 200 to 420 nm.
    • ACS exhibit high surface areas (730–2930 m²/g) and significant micropore volumes (0.28–1.12 cm³/g).
    • Remarkably high CO2 adsorption capacities of 4.55 and 8.05 mmol/g were achieved at 1 bar and 25 °C and 0 °C, respectively.

    Conclusions:

    • The developed activated carbon spheres demonstrate excellent properties for CO2 adsorption.
    • The high surface area and micropore volume contribute to the superior adsorption performance.
    • These ACS hold significant potential for effective carbon dioxide capture technologies.