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Brucite nanoplates reinforced starch bionanocomposites
Francys K V Moreira1, Daniel C A Pedro, Gregory M Glenn
1Laboratório Nacional de Nanotecnologia para o Agronegócio (LNNA), Embrapa Instrumentação (CNPDIA), São Carlos (SP), Brazil.
Carbohydrate Polymers
|February 13, 2013
Summary
Adding nano-sized brucite (Mg(OH)2) significantly enhances starch bionanocomposite films. Even low concentrations, like 1 wt.%, nearly double the elastic modulus, showcasing effective mechanical reinforcement.
Area of Science:
- Materials Science
- Polymer Science
- Nanotechnology
Background:
- Starch-based bionanocomposites are explored for sustainable material applications.
- Investigating effective reinforcing agents for biopolymers is crucial for enhancing their mechanical properties.
- Brucite, Mg(OH)2, is a mineral with potential as a nanofiller.
Purpose of the Study:
- To investigate the mechanical reinforcement of nano-sized brucite (Mg(OH)2) in starch-based bionanocomposite films.
- To evaluate the effect of brucite nanoplate dispersion and concentration on composite properties.
- To understand the interfacial interactions and reinforcement mechanisms.
Main Methods:
- Synthesis of brucite nanoplates via wet precipitation.
- Incorporation of brucite nanoplates into starch matrices at varying concentrations (0-7.5 wt.%).
- Characterization using Scanning Electron Microscopy (SEM) for dispersion and adhesion, and Thermogravimetric Analysis (TGA) for thermal stability.
Main Results:
- High dispersion of brucite nanoplates and good interfacial adhesion were observed in starch bionanocomposites.
- Brucite addition significantly increased the elastic modulus of starch films, with 1 wt.% nearly doubling it.
- Reinforcement factor exceeded Halpin-Tsai model predictions, attributed to the high surface area of nanoplates.
- Interactions between starch and brucite modified decomposition profiles.
- High reinforcing efficiency of brucite was maintained even with plasticizer addition (10-20 wt.%).
Conclusions:
- Nano-sized brucite is an effective reinforcing agent for starch bionanocomposite films.
- The high surface area of brucite nanoplates contributes significantly to mechanical enhancement.
- Starch-brucite bionanocomposites exhibit improved mechanical properties and thermal stability, with potential for plasticized applications.

