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Published on: October 10, 2013
Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(II) metal-organic
Euna Jeong1, Woo Ram Lee, Dae Won Ryu
1Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea.
Abstract:
An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO(2) uptake over N(2), H(2), and CH(4). Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units.

