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Updated: May 14, 2026

A New Approach for the Comparative Analysis of Multiprotein Complexes Based on 15N Metabolic Labeling and Quantitative Mass Spectrometry
Published on: March 13, 2014
The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
Adriano Bof de Oliveira1, Johannes Beck, Jörg Daniels
1Departamento de Química, Universidade Federal de Sergipe, Av. Marechal Rondon s/n, Campus, 49100-000 São Cristóvão-SE, Brazil.
Abstract:
The reaction of 1-amino-anthraquinone with 7,7',8,8'-tetra-cyano-quinodimethane yielded the title charge-transfer complex, C(14)H(9)NO(2)·C(12)H(4)N(4). The mol-ecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, mol-ecules are stacked into columns along the a-axis direction. Pairs of N-H⋯N and N-H⋯O inter-actions connect the mol-ecules perpendicular to the stacking direction. Additionally, an intra-molecular N-H⋯O hydrogen-bond inter-action is observed for 1-amino-anthraquinone.
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