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Related Experiment Video

Updated: May 13, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Chemically crosslinked isoreticular metal-organic frameworks.

Corinne A Allen¹, Jake A Boissonnault, Jordi Cirera

¹Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093, USA.

Chemical Communications (Cambridge, England)

|March 15, 2013

Summary

This summary is machine-generated.

Researchers synthesized novel metal-organic frameworks (MOFs) with built-in crosslinks. This new method creates isoreticular metal-organic frameworks (IRMOFs) with potentially unique properties for advanced applications.

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Area of Science:

Materials Science
Chemistry
Nanotechnology

Background:

Metal-organic frameworks (MOFs) are porous materials with diverse applications.
Isoreticular metal-organic frameworks (IRMOFs) allow for systematic tuning of pore size and properties.
Introducing interligand crosslinks can enhance MOF stability and functionality.

Purpose of the Study:

To report the synthesis of isoreticular metal-organic frameworks (IRMOFs) featuring interligand crosslinks.
To demonstrate a novel method for creating crosslinked MOF ligands.
To explore the potential for designing MOFs with tailored properties through crosslinking.

Main Methods:

Synthesis of crosslinked ligands derived from 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC).
Formation of IRMOF-1 analogs using the synthesized crosslinked ligands.
Characterization of the resulting crosslinked MOFs.

Main Results:

Successfully synthesized canonical isoreticular metal-organic frameworks (IRMOFs) containing interligand crosslinks.
Demonstrated that crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) yields effective ligands.
Produced crosslinked MOFs analogous to IRMOF-1.

Conclusions:

The developed method enables the creation of crosslinked MOFs with potential for novel properties.
This approach offers a pathway to design advanced materials by incorporating interligand crosslinks.
The synthesized crosslinked IRMOFs represent a new class of functional porous materials.