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Updated: May 12, 2026

High-Speed Magnetic Tweezers for Nanomechanical Measurements on Force-Sensitive Elements
Published on: May 12, 2023
Highly reduced double-decker single-molecule magnets exhibiting slow magnetic relaxation
Mathieu Gonidec1, Itana Krivokapic, Jose Vidal-Gancedo
1Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), 08193 Bellaterra, Spain.
Abstract:
F64Pc2Ln (1Ln, Ln = Tb or Lu) represent the first halogenated phthalocyanine double-decker lanthanide complexes, and 1Tb exhibits single-molecule magnet properties as revealed by solid-state magnetometry. The fluorine substituents of the phthalocyanine rings have a dramatic effect on the redox properties of the F64Pc2Ln complexes, namely, a stabilization of their reduced states. Electrochemical and spectroelectrochemical measurements demonstrate that the 1Tb(-/2-) and 1Tb(2-/3-) couples exhibit redox reversibility and that the 1Tb(-), 1Tb(2-) and 1Tb(3-) species may be prepared by bulk electrolysis in acetone. Low-temperature MCD studies reveal for the first time magnetization hystereses for the super-reduced dianionic and trianionic states of Pc2Ln.
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