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Studies toward the biomimetic total synthesis of (-)-PF-1018
Robert Webster1, Boris Gaspar, Peter Mayer
1Fakultät für Chemie und Pharmazie, Ludwig-Maximilians-Universität München, and Munich Center for Integrated Protein Science, Butenandtstrasse 5-13, 81377 München, Germany.
Organic Letters
|April 4, 2013
Abstract:
Pericyclic reaction cascades are unparalleled in their ability to quickly generate complex structures with excellent stereocontrol. Herein, the use of a biomimetic Stille/8π electrocyclization/Diels-Alder cascade to successfully assemble the core structure of (-)-PF-1018 is reported.
