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Microscopic origin of the optical processes in blue sapphire
Jessica K Bristow1, Stephen C Parker, C Richard A Catlow
1Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
Abstract:
Al2O3 changes from transparent to a range of intense colours depending on the chemical impurities present. In blue sapphire, Fe and Ti are incorporated; however, the chemical process that gives rise to the colour has long been debated. Atomistic modelling identifies charge transfer from Ti(III) to Fe(III) as being responsible for the characteristic blue appearance.
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