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Related Experiment Video

Updated: May 11, 2026

Automated 90Sr Separation and Preconcentration in a Lab-on-Valve System at Ppq Level
08:53

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Published on: June 6, 2018

Automated high precision secondary pH measurements.

F Bastkowski1, P T Jakobsen, F Stefan

  • 1Physikalisch-Technische Bundesanstalt (PTB), Braunschweig, Germany. frank.bastkowski@ptb.de

The Review of Scientific Instruments
|May 3, 2013
PubMed
Summary
This summary is machine-generated.

A new automated system achieves high-precision secondary pH measurements with an uncertainty better than 0.005 pH units. This method utilizes a novel thermostatted PFA cell and a flow-through design for accurate and efficient analysis.

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Area of Science:

  • Analytical Chemistry
  • Metrology

Background:

  • Accurate pH measurements are critical in various scientific and industrial applications.
  • Existing methods can be time-consuming and prone to variability.
  • Developing automated, high-precision pH measurement systems is essential for reliable results.

Purpose of the Study:

  • To develop and validate a new setup for automated secondary pH measurements.
  • To achieve a standard uncertainty in pH better than 0.005 using primary buffers as standards.
  • To establish a reference measurement procedure for interlaboratory comparisons.

Main Methods:

  • Development of a one-piece, thermostatted PFA cell with an integrated glass electrode.
  • Implementation of a flow-through principle for reduced sample consumption.
  • Utilizing a symmetric measurement sequence and two-point calibration.
  • Testing in interlaboratory comparisons with standard buffers at 25°C and 37°C.

Main Results:

  • A standard uncertainty in pH better than 0.005 was achieved.
  • The PFA cell design facilitated complete emptying and low solution consumption.
  • Precise temperature control by the tempering unit contributed to low uncertainty.
  • The system demonstrated high precision and accuracy in interlaboratory comparisons.

Conclusions:

  • The developed automated setup provides a reliable method for high-precision secondary pH measurements.
  • The novel PFA cell and precise temperature control are key to achieving low uncertainty.
  • This system offers an efficient and accurate approach for pH metrology.