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Complex three-dimensional polymer-metal core-shell structures towards emission control.

Lin Ren¹, De-Gong Wang, Li-Gang Niu

¹Information Countermeasure Department, Aviation University of Air Force, Changchun 130022, People's Republic of China.

Physical Chemistry Chemical Physics : PCCP

|May 14, 2013

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Researchers created 3D nickel nanostructures using lasers and plating. These metallic photonic crystals show thermal stability and emit light at specific wavelengths, enabling low-temperature applications.

Area of Science:

Materials Science
Nanotechnology
Photonics

Background:

Developing advanced materials for photonic applications is crucial.
Controlling nanostructure fabrication for specific optical properties remains a challenge.

Purpose of the Study:

To fabricate three-dimensional (3D) periodic metal nanostructures.
To investigate the thermal stability and optical properties of these nanostructures.

Main Methods:

Utilized femtosecond laser-induced two-photon polymerization to create polymer templates.
Employed electroless plating technology for depositing nickel onto the templates.
Controlled nickel deposition speed at 10 nm/s.
Performed optical reflectivity and thermal emission measurements up to 550 °C.

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Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides

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Published on: July 14, 2015

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Main Results:

Successfully fabricated 3D periodic nickel nanostructures with controlled deposition speed.
Demonstrated good thermal stability of the nickel-polymer structure up to 500 °C.
Observed thermal excitation and light emission at λ = 4.50, 4.95 μm at 550 °C.
Emission peaks correlated with absorption peaks, indicating photonic crystal behavior.

Conclusions:

Metallic photonic crystals can be efficiently fabricated using laser-templated electroless plating.
The method offers a simple and cost-efficient approach for creating functional nanostructures.
The fabricated emitters are suitable for low-temperature applications due to their operational characteristics.