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Odd-even effect in the elastic modulii of α,ω-alkanedicarboxylic acids
Manish Kumar Mishra1, Sunil Varughese, Upadrasta Ramamurty
1Solid State and Structural Chemistry Unit and §Department of Materials Engineering, Indian Institute of Science , Bangalore 560 012, India.
Abstract:
Nanoindentation studies on α,ω-alkanedicarboxylic acids reveal that the elastic modulus, E, shows an odd-even alternation in exactly the same manner as the melting temperature, Tm. These results are consistent with the hypothesis that the strained molecular conformations in the odd diacids are the reasons for these alternations in Tm. The same packing features that lower Tm in the odd acids lead to easy accommodation of the deformation during nanoindentation and hence their low E.
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