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Updated: May 11, 2026

Synthesis and Characterization of Supramolecular Colloids
Published on: April 22, 2016
Colloidal organization and clusters: self-assembly of polyoxometalate-surfactant complexes towards three-dimensional
S Polarz1, B Smarsly, M Antonietti
1Max Planck Institute of Colloids and Interfaces, Research Campus Golm, 14424 Potsdam, Germany. polarz@mpikg-golm.mpg.de
Abstract:
Increased hydrophobicity of well-defined polyoxometalate clusters is possible through complexation with cationic surfactants in a one-pot reaction. The clusters, of toroid and spherical shape and colloidal dimensions, then organized into ordered, supramolecular assemblies, as shown schematically, are similar to classical liquid crystals. The increased solubility in organic media opens the door to new polyoxometalate-polymer hybrid materials.
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A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules, atoms, and/or ions)...

