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Updated: May 11, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
Synthesis and structure of base-stabilized germanium(II) diazide IPrGe(N3)2
Benjamin Lyhs1, Dieter Bläser, Christoph Wölper
1Institute of Inorganic Chemistry, University of Duisburg-Essen, Universitätsstrasse 5-7, D-45117 Essen, Germany.
Abstract:
Coordination of a strong σ-base has been shown to be an effective method for the stabilization of low valent main group element complexes. This general method was now used for the synthesis of the divalent germanium diazide. IPrGe(N3)21 represents the first neutral homoleptic germanium diazide that could be structurally characterized.
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