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Related Experiment Video

Updated: May 10, 2026

Iridium(III) Luminescent Probe for Detection of the Malarial Protein Biomarker Histidine Rich Protein-II
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l-Histidinium p-toluene-sulfonate.

Srinivasan Muralidharan1, Perumal Nagapandiselvi, Thothadri Srinivasan

  • 1Department of Physics, Anna University, Chennai 600 025, India.

Acta Crystallographica. Section E, Structure Reports Online
|June 1, 2013
PubMed
Summary
This summary is machine-generated.

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The crystal structure of a salt containing imidazole and toluene rings was determined. Hydrogen bonds and C-H interactions form a 3D network, revealing molecular packing details.

Area of Science:

  • Crystallography
  • Supramolecular Chemistry

Background:

  • Understanding the packing of organic salts is crucial for materials science.
  • Imidazole and toluene derivatives are common structural motifs in various chemical compounds.

Purpose of the Study:

  • To determine the crystal structure of the title salt (C6H10N3O2 (+)·C7H7O3S(-)).
  • To investigate the intermolecular interactions governing the crystal packing.

Main Methods:

  • Single-crystal X-ray diffraction analysis was employed.
  • The crystal structure was solved and refined.

Main Results:

  • The crystal structure reveals a dihedral angle of 70.93° between the imidazole and toluene rings.
  • Two-dimensional networks are formed by N-H⋯O and C-H⋯O hydrogen bonds.

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  • These networks are further connected by C-H⋯π interactions to form a three-dimensional structure.

    • Conclusions:

    • The study elucidates the detailed supramolecular architecture of the title salt.
    • The combination of hydrogen bonding and C-H⋯π interactions dictates the formation of the 3D crystal network.