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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
[Co(I)(CN)2(CO)3]-, a new discovery from an 80-year-old reaction
Wenfeng Lo1, Chunhua Hu, Marck Lumeij
1Department of Chemistry, Yeshiva University, 2495 Amsterdam Avenue, New York, NY 10033, USA.
Abstract:
A systematic study of the 80-year-old simple and fundamental reaction of cobalt(II) salt with cyanide under one atmosphere CO was carried out and two novel Co(I) complexes were isolated in the absence of hydroxide. These complexes are the first structurally characterized mixed cobalt CO-CN(-) compounds.
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