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Combinations of ethers and B(C6F5)3 function as hydrogenation catalysts

Lindsay J Hounjet1, Christoph Bannwarth, Christian N Garon

  • 1Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6, Canada.

Angewandte Chemie (International Ed. in English)
|June 19, 2013
PubMed
Summary

Labile adducts of dialkyl ethers and the borane B(C6F5)3 facilitate hydrogen isotope scrambling and catalyze hydrogenation reactions. This discovery offers new pathways in catalytic chemistry.

Keywords:
boranesethersfrustrated Lewis pairshydrogenationorganocatalysis

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