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Updated: May 10, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
05:47

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts

Published on: August 7, 2018

Dynamic motion of Ru-polyoxometalate ions (POMs) on functionalized few-layer graphene

Xiaoxing Ke1, Stuart Turner, Mildred Quintana

  • 1Electron Microscopy for Materials Research (EMAT), University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium. xiaoxing.ke@ua.ac.be.

Small (Weinheim an Der Bergstrasse, Germany)
|July 2, 2013
PubMed
Abstract

No abstract available in PubMed .

Keywords:
dynamic behaviorfunctionalized graphenepolyoxometalatessurface chemistrytransmission electron microscopy

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...

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